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Abstract We report the first statistical analyses of [Cii] and dust continuum observations in six strong Oiabsorber fields at the end of the reionization epoch obtained by the Atacama Large Millimeter/submillimeter Array (ALMA). Combined with one [Cii] emitter reported in Wu et al., we detect one Oi-associated [Cii] emitter in six fields. At redshifts of Oiabsorbers in nondetection fields, no emitters are brighter than our detection limit within impact parameters of 50 kpc and velocity offsets between ±200 km s−1. The averaged [Cii]-detection upper limit is <0.06 Jy km s−1(3σ), corresponding to the [Cii] luminosity ofL[CII]< 5.8 × 107L⊙and the [Cii]-based star formation rate of SFR[CII]<5.5M⊙yr−1. Cosmological simulations suggest that only ∼10−2.5[Cii] emitters around Oiabsorbers have comparable SFR to our detection limit. Although the detection in one out of six fields is reported, an order of magnitude number excess of emitters obtained from our ALMA observations supports that the contribution of massive galaxies that caused the metal enrichment cannot be ignored. Further, we also found 14 tentative galaxy candidates with a signal-to-noise ratio of ≈4.3 at large impact parameters (>50 kpc) and having larger outflow velocities within ±600 km s−1. If these detections are confirmed in the future, then the mechanism of pushing metals at larger distances with higher velocities needs to be further explored from the theoretical side.more » « less
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1,3-Pentadiene (piperylene) is an important monomer in the manufacturing of adhesives, plastics, and resins. It can be derived from biomass by the tandem ring-opening and dehydration (dehydra-decyclization) of 2-methyltetrahydrofuran (2-MTHF), but competing reaction pathways and the formation of another isomer (1,4-pentadiene) have limited piperylene yields to <60%. In this report, using detailed kinetic measurements of 2-MTHF dehydra-decyclization on zeolites with disparate acidities (boro-, and alumino-silicates) and micropore environments (MFI, MWW, and BEA), weakly acidic borosilicates were shown to exhibit ca. 10–30% higher selectivity to dienes at about five-to-sixty times lower proton-normalized rates than aluminosilicates (453–573 K). Dehydra-decyclization site time yields (STYs) were invariant for aluminosilicates within the investigated frameworks, indicating the absence of pore-confinement influence. However, individual site-normalized reaction rates varied by almost an order of magnitude on borosilicates in the order MWW > MFI > BEA at a given temperature (523 K), indicating the non-identical nature of active sites in these weak solid acids. The diene distribution remained far from equilibrium and was tuned towards the desirable conjugated diene (1,3-pentadiene) by facile isomerization of 1,4-pentadiene. This tuning capability was facilitated by high bed residence times, as well as the smaller micropore sizes among the zeolite frameworks considered. The suppression of competing pathways, and promotion of 1,4-pentadiene isomerization events lead to a hitherto unreported ∼86% 1,3-pentadiene yield and an overall ∼89% combined linear C5 dienes’ yield at near quantitative (∼98%) 2-MTHF conversion on the borosilicate B-MWW, without a significant reduction in diene selectivities for at least 80 hours time-on-stream under low space velocity (0.85 g reactant per g cat. per h) and high temperature (658 K) conditions. Finally, starting with iso-conversion levels ( ca. 21–26%) and using total turnover numbers (TONs) accrued over the entire catalyst lifetime as the stability criterion, borosilicates were demonstrated to be significantly more stable than aluminosilicates under reaction conditions (∼3–6× higher TONs).more » « less
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ABSTRACT We study the evolutionary trend of the total density profile of early-type galaxies (ETGs) in IllustrisTNG. To this end, we trace ETGs from z = 0 to 4 and measure the power-law slope γ′ of the total density profile for their main progenitors. We find that their slopes γ′ steepen on average during z ∼ 4–2, then becoming shallower until z = 1, after which they remain almost constant, aside from a residual trend of becoming shallower towards z = 0. We also compare to a statistical sample of ETGs at different redshifts, selected based on their luminosity profiles and stellar masses. Due to different selection effects, the average slopes of the statistical samples follow a modified evolutionary trend. They monotonically decrease since z = 3, and after z ≈ 1, they remain nearly invariant with a mild increase towards z = 0. These evolutionary trends are mass dependent for both samples, with low-mass galaxies having in general steeper slopes than their more massive counterparts. Galaxies that transitioned to ETGs more recently have steeper mean slopes as they tend to be smaller and more compact at any given redshift. By analysing the impact of mergers and AGN feedback on the progenitors’ evolution, we conjecture a multiphase path leading to isothermality in ETGs: dissipation associated with rapid wet mergers tends to steepen γ′ from z = 4 to 2, whereas subsequent AGN feedback (especially in the kinetic mode) makes γ′ shallower again from z = 2 to 1. Afterwards, passive evolution from z = 1 to 0, mainly through gas-poor mergers, mildly decreases γ′ and maintains the overall mass distribution close to isothermal.more » « less
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ABSTRACT We explore the isothermal total density profiles of early-type galaxies (ETGs) in the IllustrisTNG simulation. For the selected 559 ETGs at z = 0 with stellar masses $$10^{10.7}\, \mathrm{M}_{\odot } \leqslant M_{\ast } \leqslant 10^{11.9}\, \mathrm{M}_{\odot }$$, the total power-law slope has a mean of 〈γ′〉 = 2.011 ± 0.007 and a scatter of $$\sigma _{\gamma ^{\prime }} = 0.171$$ over the radial range 0.4–4 times the stellar half-mass radius. Several correlations between γ′ and galactic properties including stellar mass, effective radius, stellar surface density, central velocity dispersion, central dark matter fraction, and in situ-formed stellar mass ratio are compared to observations and other simulations, revealing that IllustrisTNG reproduces many correlation trends, and in particular, γ′ is almost constant with redshift below z = 2. Through analysing IllustrisTNG model variations, we show that black hole kinetic winds are crucial to lowering γ′ and matching observed galaxy correlations. The effects of stellar winds on γ′ are subdominant compared to active galactic nucleus (AGN) feedback, and differ due to the presence of AGN feedback from previous works. The density profiles of the ETG dark matter haloes are well described by steeper than NFW profiles, and they are steeper in the full physics (FP) run than their counterparts in the dark matter-only (DMO) run. Their inner density slopes anticorrelate (remain constant) with the halo mass in the FP (DMO) run, and anticorrelate with the halo concentration parameter c200 in both the types of runs. The dark matter haloes of low-mass ETGs are contracted whereas high-mass ETGs are expanded, suggesting that variations in the total density profile occur through the different halo responses to baryons.more » « less
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